Micellar-Enhanced Ultrafiltration and Air Stripping for Surfactant-Contaminant Separation and Surfactant Reuse   总被引：2，自引：0，他引：2  

K. Michelle Lipe  David A. Sabatini  Mark A. Hasegawa  Jeffrey H. Harwell 《Ground Water Monitoring & Remediation》1996,16(1):85-92

Micellar-enhanced ultrafiltration (MELT) and air stripping were evaluated for surfactant-contaminant separation and surfactant recovery. Two linear alkyl diphenyloxide disulfonate (DPDS) surfactants were evaluated with the contaminants naphthalene and trichloroethylene. A separation model developed from micellar partitioning principles showed a good correlation to batch MEUF studies, whereas flux analysis highlighted concentration polarization effects in relation to hydrophobe length. MEUF effectively concentrated the surfactant-contaminant system (93 to 99 percent retention); however, this did not result in surfactant-contaminant separation. Batch and continuous flow air stripping models were developed based upon air/water ratio, surfactant concentration, and Micellar partitioning; model predictions were validated by experimental data. Sensitivity analyses illustrated the decline in contaminant-surfactant separation with increasing surfactant concentration (e.g., TCE removal efficiency declines from 83 percent to 37 percent as C-16 DPDS concentration increases from 0 to 55 mM). This effect is greater for more hydrophobic contaminants (naphthalene vs. TCE) and surfactants with greater solubilization potential (C16-DPDS vs. C-12 DPDS). The resulting design equations can account for this effect and thus properly size air strippers to achieve the desired removal efficiency in the presence of surfactant micelles. Proper selection and design of surfactant-contaminant separation and surfactant recovery systems are integral to optimizing surfactant-enhanced subsurface remediation.  相似文献   

Thermal analysis in the laser-heated diamond anvil cell     

Jeffrey S. Sweeney  Dion L. Heinz 《Pure and Applied Geophysics》1993,141(2-4):497-507

A new technique actively controls thermal radiation and monitors sample properties during laser-heating in a diamond anvil cell. The technique can be described as a qualitative application of thermal analysis. Discontinuities in temperature, laser power, visible thermal radiation, or in their derivatives as functions of time can be associated with the enthalpy of phase transitions (such as melting) or with changes in maternal properties (such as emissivity).The technique is illustrated with melting experiments on iron-magnesium-silicate perovskite. Temperature corrections associated with these experiments are discussed and the results are briefly reviewed.  相似文献   

Multivariate Geostatistïcal Analysis of Ground-Water Contamination: A Case History     

Jonathan D. Istok  Jeffrey D. Smyth  Alan L. Flint 《Ground water》1993,31(1):63-74

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Influence of Rhodamine WT Properties on Sorption and Transport in Subsurface Media   总被引：2，自引：0，他引：2  

Bor-Jier Shiau  David A. Sabatini  Jeffrey H. Harwell 《Ground water》1993,31(6):913-920

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A Numerical Model Study of Ground-Water Contamination from Price's Landfill, New Jersey— I. Data Base and Flow Simulation     

William G. Gray  Jeffrey L. Hoffman 《Ground water》1983,21(1):7-14

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Major and trace elements in igneous rocks from apollo 15     

Philip A. Helmke  Douglas P. Blanchard  Larry A. Haskin  Karen Telander  Charles Weiss  Jeffrey W. Jacobs 《Earth, Moon, and Planets》1973,8(1-2):129-148

The concentrations of major and trace elements have been determined in igneous rocks from Apollo 15. All materials analyzed have typical depletions of Eu except for minerals separated from sample 15085. Four samples have concentrations of trace elements that are similar to those of KREEP. The samples of mare basalt from Apollo 15 have higher concentrations of FeO, MgO, Mn, and Cr and lower concentrations of CaO, Na₂O, K₂O, and rare-earth elements (REE) as compared to the samples of mare basalt from Apollos 11, 12, and 14. The samples can be divided into two groups on the basis of their normative compositions. One group is quartz normative and has low concentrations of FeO while the other is olivine normative and has high concentrations of FeO. The trace element data indicate that the samples of olivine normative basalt could be from different portions of a single lava flow. At least two and possible three parent magmas can be identified from the samples of the quartz normative group on the basis of their concentration ratios of Sm to Eu. Within each group, the compositions of the samples appear to be related by crystallization of olivine or pyroxene. Significant variations of the ratio of concentration of Sm to Eu cannot be produced without plagioclase-liquid equilibrium. The source material of mare basalt may be depleted in Eu. Alternatively, the magmas may have assimilated a small volume of material similar to KREEP.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.  相似文献   

Ultraviolet spectroscopy of the outer layers of stars     

Theodore P. Snow Jr.  Jeffrey L. Linsky 《Astrophysics and Space Science》1980,67(2):285-307

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The response of fishes to submerged aquatic vegetation complexity in two ecoregions of the mid-Atlantic bight: Buzzards Bay and Chesapeake Bay     

Jason C. Wyda  Linda A. Deegan  Jeffrey E. Hughes  Melissa J. Weaver 《Estuaries and Coasts》2002,25(1):86-100

Estuarine seagrass ecosystems provide important habitat for fish and invertebrates and changes in these systems may alter their ability to support fish. The response of fish assemblages to alteration of eelgrass (Zostera marina) ecosystems in two ecoregions of the Mid-Atlantic Bight (Buzzards Bay and Chesapeake Bay) was evaluated by sampling historical eelgrass sites that currently span a broad range of stress and habitat quality. In two widely separated ecoregions with very different fish faunas, degradation and loss of submerged aquatic vegetation (SAV) habitat has lead to declines in fish standing stock and species richness. The abundance, biomass, and species richness of the fish assemblage were significantly higher at sites that have high levels of eelgrass habitat complexity (biomass >100 wet g m^?2; density <100 shotts m^?2) compared to sites that have reduced eelgrass (biomass <100 wet g m^?2; density <100 shoots m^?2) or that have completely lost eelgrass. Abundance, biomass, and species richness at reduced eelgrass complexity sites also were more variable than at high eelgrass complexity habitats. Low SAV complexity sites had higher proportions of pelagic species that are not dependent on benthic habitat structure for feeding or refuge. Most species had greater abundance and were found more frequently at sites that have eelgrass. The replacement of SAV habitats by benthic macroalgae, which occurred in Buzzards Bay but not Chesapeake Bay, did not provide an equivalent habitat to seagrass. Nutrient enrichment-related degradation of eelgrass habitat has diminished the overall capacity of estuaries to support fish populations.  相似文献   

Episodes of late Holocene aridity recorded by stalagmites from Devil's Icebox Cave, central Missouri, USA   总被引：1，自引：0，他引：1  

Rhawn F. Denniston  Michelle DuPree  Jeffrey A. Dorale  Victor J. Polyak 《Quaternary Research》2007,68(1):45-52

Two stalagmites from Devil's Icebox Cave, central Missouri, display similar δ¹³C and δ¹⁸O values and trends during the late Holocene. Positive δ¹³C excursions at 3.5-2.6 ka and 1.2-0.9 ka are interpreted to reflect drier conditions. These elevated stalagmite δ¹³C values could have plausibly been driven by increasing C₄ plant abundances over the cave or an increased contribution of bedrock carbon, both of which could reflect decreased effective moisture. A lack of corresponding oxygen isotopic anomalies during these intervals suggests that neither mean annual temperature nor the seasonality of precipitation changed concomitantly with dryness. Both of the δ¹³C excursions identified in our stalagmite record are roughly coincident with dry intervals from a number of sites located across the Great Plains.  相似文献   

Enter the working forest: Discourse analysis in the Northern Forest     

Steven A. Wolf  Jeffrey A. Klein 《Geoforum》2007,38(5):985-998

In 1988, four states in the northeastern USA commissioned a study to address land use changes in the Northern Forest, 26 million acres of temperate and boreal forest extending from Maine to eastern New York State. Against a backdrop of economic destabilization and concerns regarding social and ecological implications of a real estate boom, the sustained deliberative dialogue catalyzed by this study has come to rely heavily on the ambiguous concept of “working forest.” To clarify political and environmental dynamics in the region, we analyzed how people respond to and seek to capitalize on the interpretive flexibility of the term working forest. We combine an analysis of socio-political discourses of working forest based on a structured literature review with an assessment of local peoples’ definitions of working forest based on a survey conducted in a pair of contrasting New York State communities. The first study site represents an amenity-oriented community (i.e. a place where the forest supports a service economy including recreation and tourism) and the other study site represents a timber-dependent community. By linking data from community-level analysis to data derived from a general analysis of forest politics, we seek to develop a more robust perspective. By comparing discourses across differently structured communities, we investigate how local forest politics are mediated by local economic development processes. Our study empirically illustrates contested and geographically uneven processes of social construction of environment and rural development in a region confronting pressures of globalization. Results indicate that timber harvesting is a heavily privileged management objective, as a logic of ‘the forest that pays is the forest that stays’ dominates. Environmental politics in the region, and perhaps more generally, increasingly conforms to a form of pragmatism in which economic opportunities structure conservation planning and investment.  相似文献